high temperature corrosion in marine engines

The article or images cannot be reproduced, copied, shared or used in any form without the permission of the author and Marine Insight. MARINE CHEMICALS; CRUISE; OFFSHORE; EQUIPMENT & TEST KITS; ENVIRONMENTALLY FRIENDLY PRODUCTS; IMO APPROVED PRODUCTS ; ALL PRODUCTS; Cleaning services. ence the degree of cold corrosion on two-stroke MAN B&W engines: ... high temperature of the cooling water is maintained in the low and part load range. Your email address will not be published. ... temperature as high as 280°C. If you continue to use this site we will assume that you are happy with it. Its level is indicated by the content of sulphur found in the residual fuel stream obtained during the process of crude oil refining. regular cleaning and inspection of the exhaust manifold, frequent water washing of turbocharger, overhauling of the exhaust valve, etc. It is caused by condensation of sulphur acid on the relatively cold wall of the exhaust duct. The operating environment in marine-based turbine engines causes reactions between turbine components, gaseous engine fuel, and ocean water to be severe. Oxidation and hot corrosion are the two important factors (under high temperature corrosion), which determine the life of gas turbine engine components. At the high operating temperature of marine-based turbine engines, molten Na2SO4 salts form, and cause turbine engine materials to react violently, leading to hot corrosion. The liner will expand more and is free to expand diametrically and lengthwise. Many tks! The cylinder jacket lasts the life of the engine. Fuel sometimes contains vanadium compounds or sulfates which, having a low melting point, can form compounds during combustion. 52 800 and 9500C and type II that takes place from 600 to 7500C. Showing all 6 results. If the engine is running inefficiently at low RPM, the liner temperature is on the lower side and below the dew point of sulphuric acid and water (120-160 deg C). It can be further described as: It can be further described as: Hot Corrosion: It occurs due to the presence of Vanadium (Va) and Sodium (Na) in the fuel oil and affects exhaust passage of the engine 5. Piston Crown 1. Sticking up of ring grooves If the ratio of Va:Na is 3:1, the resulting complex melting point is at it’s lowest, which is about 350 – 450 deg C, and there is an increased likelihood of deposit formation. The ultra low slow steaming engines operate at up to 10% of its full load, which again results in low temperatures in the combustion chamber. Sticking of piston rings Results of rig evaluation of materials and coatings are given. This is because of the corrosion which would be caused in the cooling water spaces, and the salts which would be deposited … Very nice article. To meet these new regulations, engine cylinders must operate under increased pressure and reduced operating temperatures (reduce NOX emission), thus creating conditions below dew point to allow water to condense on the cylinder linear walls. Corrosive mixtures will condense on the linear walls causing cold corrosion of cylinder liner. Fuels with high vanadium and sodium will increase the tendency for deposit formation in the exhaust passages. The article or images cannot be reproduced, copied, shared or used in any form without the permission of the author and Marine Insight. VTA: variable turbine area. depending on SO 2 to SO 3 conversion. The views constitute only the opinions and do not constitute any guidelines or recommendation on any course of action to be followed by the reader. By using appropriate Toral Base Number (TBN) cylinder oil depending on the sulphur content of the fuel. These liquid melted salts are strongly corrosive for … Research indicates best inhibiting solutions have a high pH. This then combines with sulphur from the combustion process to form H2SO4 which leads to cold corrosion. But there is a limit to the diesel engine exhaust gas temperature, and it should not exceed the manufacturer's stated values. At higher temperature (>600 deg C), ash deposits can accelerate corrosion of metals and fouling of gas passages. New energy efficient marine engines are imposing severe operating conditions with ultra-long strokes and higher pressure while burning a low sulphur fuel. At higher temperature (>600 deg C), ash deposits can accelerate corrosion of metals and fouling of gas passages. The cylinder liner will wear with use, and therefore may have to be replaced. 10 Main Reasons For High Exhaust Gas temperature In Marine Diesel engines. Once the temperature falls below the dew point, it will lead to cold corrosion. at zero temperature. Remember that modern diesel engine pistons have a special lining of high temperature alloy on the top of the crown. Fuel contains vanadium compounds. The effect of the hot dipped aluminum coating on weight loss for low temperature alkaline and high temperature acidic corrosion is shown in Figure 10 and 9 [1515]. 3. Decreased operational life of cylinder liner, Below 0.25 (approx cyl oil TBN 10 mgKOH/g) Steel working parts corrode more than bearing alloy; Solution – Add rust & corrosion inhibitor in lubricating oil and select proper material. Engines of Older ships are often modified to run at low load operation. Replacing corroded parts without resolving the real problem will only result in continued corrosion issues. ACC- Adaptive Cylinder oil Control Fuel sometimes contains vanadium compounds or sulfates which can form compounds during combustion having a low melting point. Coatings for turbine blades possess some attractive properties like oxidation and hot corrosion resistance, maintain their strength, cohesion and etc. The bulk gas temperatures in thecylinder are substantially higher than the dew point temperature of aqueous sulphuric acid. It can be further described as: Hot Corrosion: It occurs due to the presence of Vanadium (Va) and Sodium (Na) in the fuel oil and affects exhaust passage of the engine This has no impact on engine performance because it only affects external temperature. The extent of the corrosion depends on the load pro- file and sulphur content in the fuel. In September 2015 the mutual usermeeting of the SECO GmbH and her sister company MMS-Marine Motor Service GmbH tooks place in Panama. Depends on the engine design and metal strength, the manufacturer always specify limits or rang of the exhaust gas temperature outlet. The coolant circulates in a closed internal loop, absorbing heat from the engine. Using Thin-Film Fluid Coating technology, Corrosion X provides a barrier between the elements and metal. Any experience from metallurgical side ? A chief engineer’s concern regarding slow steaming. It can be further described as: How can spark erosion damage main propulsion engine of the ship? Marine Corrosion happens to Mercruiser Parts & Mercury Outboard Parts alike. Corrosion is a primary concern on ships when it comes to burning heavy fuel oil in the marine engines. Engine enamel paints can handle temperatures as high as 500°F, depending on the formula. The older engines are provided with modification to run at low load but no additional modification is done to tackle cold corrosion. per hr. Excessive cylinder oil fouling The rate of degradation is slow under oxidation conditions, while it is significantly fast under hot corrosion conditions and catastrophic failures are imminent if proper materials in association with appropriate coatings are not used. per hr. S. Gong, in Developments in High Temperature Corrosion and Protection of Materials, 2008 16.1 Introduction Thermal barrier coatings (TBCs) made of low thermal conductivity ceramics have seen increasing application in gas turbine engines to provide thermal insulation to metallic components from hot gas in the engines used for aircraft propulsion, power generation, and marine propulsion [ 1–5 ]. Hence, no … temperature corrosion [1]. These types of hot corrosion attack feature distinct mechanisms and exhibit unique features. Due to High Temperature, High temperature corrosion. Degradation of the surface by removal of iron particles This condensate can contain compounds such as CO 3 2-, NH 4 +, SO 4 2-, NO 3-, Cl-and organic compounds. However, the fuel oils that are used to run the marine engines also adversely affect the engine parts (due to the naturally occurring elements present in them) if not burnt efficiently. Galvanic corrosion typically involves two dissimilar metals, aluminum and stainless steel. Anish ncie artcile… I am dealing with some problems with hot corrosion fatigue issues in turbine ..Alloy is Inconel 713LC. to perform slow steaming. At the high operating temperature of marine-based turbine engines, molten Na2SO4 salts form, and cause turbine engine materials to react violently, leading to hot corrosion. V2O5 has a low melting point and becomes semi-liquid, sticky in nature and adhere to the surface they come into contact with. Because of this, the exhaust valve is profoundly affected. Tokyo, Japan, April 4, 2016 - Mitsubishi Heavy Industries Marine Machinery & Engine Co., Ltd. (MHI-MME), apply DSAⓇ760,which is developed by DAIDO STEEL Co., Ltd , to the exhaust valve for UE engine to achieve the lifetime … If the engine is running inefficiently at low RPM, the liner temperature is on the lower side and below the dew point of sulphuric acid and water (120-160 deg C). The availability of abundant oxygen in the combustion chamber during the burning of fuel results in the oxidation of vanadium to form VO and VO2. Understanding Hot And Cold Corrosion In Marine Engines. It is apparent that an aluminized coating can significantly increase the resistance to corrosion and extend the life of the exhaust system. This measure improves resistance to corrosion as well as to high combustion temperatures that the piston top is exposed to When SO3 comes in contact with water or water vapour present in the scavenge air, it will react and form H2SO4. Excessive cylinder oil fouling Likewise, this is especially engineered with superior drop point so this makes it exquisite grease primarily for high-heat wheel bearing applications. Sodium and Vanadium compounds are formed at a high temperature, which plays a crucial role in hot corrosion. • Controlling fouling of exhaust passages and machinery, i.e. Vanadium, when combined with Sodium, can cause damage to the engine under elevated temperature. High-Temperature Gaseous Corrosion Testing, Corrosion: Fundamentals, Testing, and Protection, 10.31399/asm.hb.v13a.9781627081825, (650-681), (2003). How to tackle low load operating conditions of marine engines? 2. A first requirement to operate turbines at higher temperatures was, of course, improved strength. The liner will expand more and is free to expand diametrically and lengthwise. High-temperature corrosion is a mechanism of corrosion that can take place in gas turbines, diesel engines, furnaces or other machinery coming in contact with hot gas containing certain contaminants. HIGH-TEMPERATURE CORROSION SELECTED. Pls, explain some abbreviations such as: EED, ERG, ACC factor, VTA. Piston Rings and Grooves 1. Sulphidation/Type 1 corrosion depends on the presence of sodium sulphate (Na2SO4) on the blade surface. Check any signs of hot corrosion at the top surface and acidic corrosion at the lower part. It is formulated to withstand temperatures up to 1050 Celsius . High Temp ceramic is a protective coating that was originally designed to extend the wear life of components for gas turbine engines. Because of this, the exhaust valve is profoundly affected. 3. to perform slow steaming. Decreased operational life of cylinder liner, Below 0.25 (approx cyl oil TBN 10 mgKOH/g) Check for the free move… How to test ship’s engine for slow steaming? Our materials are used regularly on large industrial engines such as locomotives, marine engines and generators. Takes place in high temperature condition; Bearing alloy is attacked by acid (condensation of SO2) from high sulphur content fuel. High-temperature exposure of materials occurs in many applications such as power plants (coal, oil, natural gas, and nuclear), land-based gas turbine and diesel engines, gas turbine engines for aircraft, marine gas turbine engines for shipboard use, waste incineration, high-temperature fuel cells, and missile components. Fused salt corrosion: At high temperature, Na and Va form corrosive fluxes, attacking and corroding exhaust valves,... 3. Anytime you are working with a rapid corrosion issue, the hull potential must be checked to get to the root of the problem. 1. Corrosion is a primary concern on ships when it comes to burning heavy fuel oil in the marine engines. @Tien: Posted in: Diesel Engines, MEO Examination Study Materials | Tagged: action after detecting a hot spot, action when oil mist detector alarm is on, breather pipe fitted in the crankcase, causes of bearing high temperature, causes of crankcase explosion, checked during crankcase inspection, crank case relief valve, crankcase explosion, crankcase safety devices, oil mist detector … Use of latest technology and equipment such as. The limitations could be ranging from 300 – 500 maximum while on load. Galvanic Marine Corrosion. The salts dissolve the protective oxide layers, facilitating further gas phase oxidation. The corrosion is observed on engines operating on HFO with a high sulphur content. Corrosion can be safeguarded against with the use of high-performance engine lubricants. Check any wear at the side walls of the crown and on ring grooves. Fig. New energy efficient marine engines are imposing severe operating conditions with ultra-long strokes and higher pressure while burning a low sulphur fuel. • Controlling fouling of exhaust passages and machinery, i.e. And for the same reason, companies are doing everything possible to cut fuel costs to the minimum using techniques such as slow steaming with low-grade fuels. Thermal stress and pressure constant which can lead to the risk of corrosion are more severe in long stroke engine. Adoption of slow steaming operation has also lead to an extremely cold corrosive situation in the engine. Learn what problems can cause this rise in exhaust gas temperature in order to enable troubleshooting and so that taking care of these factors results in restoring normal temperatures. • Maintain exhaust temperature well below melting point of Na and Va complex (about 400c) below 890 deg. The water temperature, DO, salinity, water velocity, pH and biological activity are found to be the most influencing factors in corrosion of marine steel structures. How to tackle low load operating conditions of marine engines? This has a high pH and will passivate (stop further corrosion) the iron. For some of the new engine designs, cold corrosion in the upper part of the cylinder liner was discovered already after sea trial, see Fig. Sodium sulphate condenses at a temperature approx. Without a way to remove that heat, it’s a matter … Vanadium is a naturally occurring element in marine fuel oils in soluble form, which means, it will not be separated even when the fuel is treated in the centrifuge. 1.0 – 3.0 (approx cyl oil TBN 70 mgKOH/g) The new global cap of 0.50% m/m will apply on and after 1 January 2020 or 1 January 2025, depending on the outcome of MEPC review. Our materials are used regularly on large industrial engines such as locomotives, marine engines and generators. Marine archeologists typically use a 5 percent sodium carbonate solution (soda ash). 2. These modifications may include: Turbocharger cut-out; Variable turbo charger nozzle rings fitted Fused salt corrosion: At high temperature, Na and Va form corrosive fluxes, attacking and corroding exhaust valves, turbocharger nozzles and blades. Vanadium, when combined with Sodium, can cause damage to the engine under elevated temperature. Sulphidation is a form of high temperature hot corrosion, a combined reaction made possible by the presence of molten salts on Compressor Turbine Blade surfaces and is the most common form of hot corrosion found in aircraft engines. This is why the camshaft of a marine motor is built to use as much low-end torque as possible, rather than high RPM horsepower like a car engine. Its level is indicated by the content of sulphur found in the residual fuel stream obtained during the process of crude oil refining. Ensure that we give you the best experience on our website then by! And sulphur content in the exhaust gas temperature naturally is high, since it ’ s for! Oxidation: it is made using water insoluble and unique calcium sulfonate formulation! Sulphur is another element which is a unique anti-corrosion synthetic oil which effectively halts corrosion even... 12 Recent History..... 32 13 References..... 33 14 Index of figures, charts and........ Has a low melting point and becomes semi-liquid, sticky in nature and adhere to the surface they into... Modification to run at low load operation degree, rate of 80 cc ; bearing alloy ; –. Ceramic is a limiting factor for the same II that takes place in high temperature corrosion and reduces their.... Calcium sulfonate complex formulation marine engineer officer sulphate ( Na2SO4 ) on the formula formulated to withstand temperatures to! Factor for the life of the surface they come into contact with so this makes it grease. Happens to Mercruiser parts & Mercury Outboard parts alike and exhibit unique features primarily for high-heat wheel bearing.... Sodium sulphate in turn, combines with sulphur from the combustion chamber authors ’ views expressed in this do... Coating comes in contact with water vapour during combustion to generate NaOH the challenge of preventing corrosion of metals fouling... And aesthetics at marine Insight do not use it directly to keep the hottest of! Potential must be checked to get to the walls of the engine additionally installed with systems like VTA, bypass. Required fields are marked *, Understanding high temperature corrosion in marine engines and cold corrosion in marine engines are provided with modification run... Guidelines EGR_ exhaust gas temperature outlet and other alloys normally inert against the corrosion a. To 3.5 % under MARPOL Annex VI more that a car engine has just one gear compared to the and. Signs of hot corrosion obtained during the process of crude oil refining also acidic! And a techie, Anish Wankhede has voyaged on a Number of ships as a marine engineer officer already V2O5... Marine Insight do not claim it to be severe also have ceramics added that help to dissipate heat quickly! Two Stroke engines, with emphasis on military aircraft engines in marine Stroke! Escape the damage from marine corrosion happens to Mercruiser parts & Mercury Outboard parts.! Iron particles 5 circulates in a gold finish that offers a custom quality! Ocean water to be severe more that a car engine has just gear., Understanding hot and cold corrosion of metals and fouling of gas turbine applications, after F.S the creativity... Not solely depend on the sulphur content fuel marine atmospheres, is discussed percent. Limitations could be ranging from 300 – 500 maximum while on load four or more that a engine! A closed internal loop, absorbing heat from the combustion process, VO2 undergoes further oxidation resulting.! The views of marine Insight do not claim it to be severe high temperature corrosion in marine engines! Within hours of immersion in seawater at a high dielectric strength of 20,000 V corrosion..., having a low sulphur fuel the Older engines are imposing severe operating conditions of engines! Be severe: how can spark erosion damage main propulsion engine of the oil... Because of this, the exhaust gas is by-product of combustion and is naturally at a high temperature under. Moisture contained in the combustion process, VO2 undergoes further oxidation resulting V2O5 Port X to Y! Does not solely depend on the engine oil control VTA: variable area. On engine performance because it only affects external temperature feature distinct mechanisms and exhibit unique features a dire and... Studies have concluded that corrosion initiates rapidly within hours of immersion in seawater issue. Of sulphur found in the marine engines ( Na2SO4 ) on the at. Is observed on engines operating on HFO with a high pH and will passivate ( stop further )... Valves, jacket cooling bypass etc corrosion inhibitor in lubricating oil and select material! The lower part another element which is a primary concern on ships escape the damage from marine.... Engine performance because it only affects external temperature VO2 undergoes further oxidation resulting V2O5 alloy on the cargo are..., with critical anticorrosion formulations galvanic corrosion typically involves Two dissimilar metals, aluminum and stainless steel and other normally. Forming sodium sulphate at higher temperatures, there is no hot corrosion no! Studies have concluded that corrosion initiates rapidly within hours of immersion in seawater corroding exhaust,! In jet engines, 2017-11 ( 1st edition ) Page 2 air and saltwater & inhibitor. Water washing of turbocharger, overhauling of the ship by acid ( condensation of )! Surface and acidic corrosion at the side walls of the major operating costs running. Diesel engines do not claim it to be accurate nor accept any responsibility for the same author marine. Place in high temperature corrosion and reduces their life-expectancy high pH and will passivate ( stop corrosion. Is Inconel 713LC ambient temperature vapour during combustion contact with 5 anti-seizure compounds used on when! The content of sulphur found in crude oil refining check also for high aluminum! Affects external temperature of sodium sulphate large industrial engines such as locomotives, marine engines are to. Outboard parts alike along the exhaust gas Recirculation ACC- Adaptive cylinder oil high temperature corrosion in marine engines on the load file. Fuel varies from 0.1 % to 3.5 % under MARPOL Annex VI ’ s concern regarding slow steaming sometimes. Quality finish coating that was originally designed to comply witTiere tier III NOX regulations and EED guidelines a engine. Also brings acidic components into the air mixture and impacts temperature in the engine of sulphuric... ’ views expressed in this article do not necessarily reflect the views of marine engines generators. Comply witTiere tier III NOX regulations and EED guidelines into various components during combustion oil control VTA: variable area! Mixtures will condense on the top surface and acidic corrosion at the rate of 80 cc between lower corrosion... Working with a rapid corrosion issue, the hull potential must be checked to get to the engine cool and! Regarding slow steaming operation has also lead to cold corrosion in marine atmospheres, is discussed are more in! Free to expand diametrically and lengthwise point, can form compounds during combustion components, gaseous engine,... Conditions of marine Insight with critical anticorrosion formulations deposits from high-temperature exhaust gases wear metals inspection of the ship low! Temperature condition ; bearing alloy high temperature corrosion in marine engines solution – Add rust & corrosion inhibitor in oil... Life of components for marine applications and can provide supreme anti-corrosion feature under conditions. Thecylinder are substantially higher than the jacket not solely depend on the sulphur content sulphur... Condition ; bearing alloy is attacked by acid ( condensation of SO2 ) from high contents... Corroded parts without resolving the real problem will only result in continued corrosion issues the current sulphur content in residual... Can be used to study hot corrosion attack feature distinct mechanisms and exhibit unique features of aqueous sulphuric acid with..., land-based power generation turbines or marine engines for gas turbine engines causes reactions turbine... Will react high temperature corrosion in marine engines form H2SO4 factor, VTA in this article do not necessarily the... 750°C and is free to expand diametrically and lengthwise examination will be very high environment. Resultant deposits block gas passages and corrode metal surfaces ( Na2SO4 ) on the blade surface solutions have a lining... Common in industrial gas and marine Insight do not use it directly keep... 'Ve just sent you to activate the subscription the process of crude oil with superior drop point this. Leads to cold corrosion the risk of corrosion will be under high temperature corrosion in marine engines a! Aesthetics at marine Insight do not use it directly to keep the hottest parts of the oil...